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激光表面改性技术发展研究

张群莉,王梁,梅雪松,姚建华

《中国工程科学》 2020年第22卷第3期页码 71-77 doi: 10.15302/J-SSCAE-2020.03.010

摘要：

激光表面改性技术利用高能量密度的激光束对零部件局部易损易耗区域进行快速处理，获得材料表面所需性能，进而大幅延长零部件使用寿命，已在航空航天、石油化工、能源、交通、冶金等领域获得应用。本文针对激光冲击强化、激光淬火、激光熔覆3 种典型的激光表面改性技术，梳理了相应技术特点及国内外应用现状，凝练我国相关技术领域面临的差距与问题，总结激光表面改性技术的重点发展方向：专用合金材料制备、多能场激光复合表面改性、面向现场的激光再制造、激光冲击强化控形控性、激光表面改性智能化、激光表面微结构化。从政府引导、国产化创新、产业链完善、质量评价标准体系、人才培养等方面提出发展建议，以期为我国激光表面改性技术发展提供参考借鉴。

关键词：激光表面改性冲击强化淬火熔覆发展趋势

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Process improvement in laser hot wire cladding for martensitic stainless steel based on the Taguchi method

Zilin HUANG,Gang WANG,Shaopeng WEI,Changhong LI,Yiming RONG

《机械工程前沿（英文）》 2016年第11卷第3期页码 242-249 doi: 10.1007/s11465-016-0397-7

摘要：

Laser hot wire cladding, with the prominent features of low heat input, high energy efficiency, and high precision, is widely used for remanufacturing metal parts. The cladding process, however, needs to be improved by using a quantitative method. In this work, volumetric defect ratio was proposed as the criterion to describe the integrity of forming quality for cladding layers. Laser deposition experiments with FV520B, one of martensitic stainless steels, were designed by using the Taguchi method. Four process variables, namely, laser power (P), scanning speed (V_s), wire feed rate (V_f), and wire current (I), were optimized based on the analysis of signal-to-noise (S/N) ratio. Metallurgic observation of cladding layer was conducted to compare the forming quality and to validate the analysis method. A stable and continuous process with the optimum parameter combination produced uniform microstructure with minimal defects and cracks, which resulted in a good metallurgical bonding interface.

关键词： process optimization Taguchi method signal-to-noise (S/N) ratio volumetric defect ratio laser hot wire cladding

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The Application and the Prospect of Remanufacturing Technologies in the Metallurgical Industry

Jie Xiong,Jian-cheng Fan,Jv Yuan

《工程管理前沿（英文）》 2016年第3卷第2期页码 165-170 doi: 10.15302/J-FEM-2016023

摘要： Metallurgical equipment is subjected to severe working conditions and the components suffer from various types of physical damages such as abrasion, corrosion and crack. Advanced surface engineering technologies and resistant coatings on the damaged surface can improve surface properties, extend service lives, reduce maintenance costs and improve product quality in the metallurgical industry. This paper introduces remanufacturing technologies, including electroplating, overlaying welding, thermal spraying and laser surface cladding and their applications in the metallurgical industry, and analyzes the development tendency and prospect of remanufacturing technologies.

关键词： remanufacturing technology electroplating overlaying welding thermal spraying laser surface cladding

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Hybrid forming mechanism of patternless casting and laser cladding

Zhongde SHAN, Fuzhen SUN, Yang LIU

《机械工程前沿（英文）》 2019年第14卷第4期页码 393-401 doi: 10.1007/s11465-019-0550-1

摘要： In accordance with the requirement of manufacturing dies quickly and economically, a hybrid forming method of stamping dies for automobile panels is proposed. The method combines digital patternless casting and high-power laser cladding. An experimental study is conducted on the hybrid forming process and its trial production and application in the manufacturing of stamping dies for typical panels. Results prove that the laser cladding layer exceeds HRC60 (Rockwell hardness) and thus meets the production efficiency requirement of automobile dies. The rate of defects is well controlled. Compared with traditional technology, this technology has remarkable advantages and advancement.

关键词： patternless casting laser cladding hybrid forming rapid tooling

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Construction of nitrogen-doped carbon cladding LiMnO film electrode with enhanced stability for electrochemically

《化学科学与工程前沿（英文）》 2023年第17卷第12期页码 2050-2060 doi: 10.1007/s11705-023-2343-7

摘要： Reducing the dissolution of Mn from LiMn₂O₄ (LMO) and enhancing the stability of film electrodes are critical and challenging for Li⁺ ions selective extraction via electrochemically switched ion exchange technology. In this work, we prepared a nitrogen-doped carbon cladding LMO (C-N@LMO) by polymerization of polypyrrole and high-temperature annealing in the N₂ gas to achieve the above purpose. The modified C-N@LMO film electrode exhibited lower Mn dissolution and better cyclic stability than the LMO film electrode. The dissolution ratio of Mn from the C-N@LMO film electrode decreased by 42% compared to the LMO film electrode after 10 cycles. The cladding layer not only acted as a protective layer but also functioned as a conductive shell, accelerating the migration rate of Li⁺ ions. The intercalation equilibrium time of the C-N@LMO film electrode reached within an hour during the extraction of Li⁺ ions, which was 33% less compared to the pure LMO film electrode. Meanwhile, the C-N@LMO film electrode retained evident selectivity toward Li⁺ ions, and the separation factor was 118.38 for Li⁺ toward Mg²⁺ in simulated brine. Therefore, the C-N@LMO film electrode would be a promising candidate for the recovery of Li⁺ ions from salt lakes.

关键词： LiMn₂O₄ lithium extraction surface coating cyclic stability Mn dissolution

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Advances in polishing of internal structures on parts made by laser-based powder bed fusion

《机械工程前沿（英文）》 2023年第18卷第1期 doi: 10.1007/s11465-022-0724-0

摘要： The internal structures of metallic products are important in realizing functional applications. Considering the manufacturing of inner structures, laser-based powder bed fusion (L-PBF) is an attractive approach because its layering principle enables the fabrication of parts with customized interior structures. However, the inferior surface quality of L-PBF components hinders its productization progress seriously. In this article, process, basic forms, and applications relevant to L-PBF internal structures are reviewed comprehensively. The causes of poor surface quality and differences in the microstructure and property of the surface features of L-PBF inner structures are presented to provide a perspective of their surface characteristics. Various polishing technologies for L-PBF components with inner structures are presented, whereas their strengths and weaknesses are summarized along with a discussion on the challenges and prospects for improving the interior surface quality of L-PBF parts.

关键词： laser-based powder bed fusion polishing internal structures surface quality surface features post process additive manufacturing

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Review on mechanism and process of surface polishing using lasers

Arun KRISHNAN, Fengzhou FANG

《机械工程前沿（英文）》 2019年第14卷第3期页码 299-319 doi: 10.1007/s11465-019-0535-0

摘要： Laser polishing is a technology of smoothening the surface of various materials with highly intense laser beams. When these beams impact on the material surface to be polished, the surface starts to be melted due to the high temperature. The melted material is then relocated from the ‘peaks to valleys’ under the multidirectional action of surface tension. By varying the process parameters such as beam intensity, energy density, spot diameter, and feed rate, different rates of surface roughness can be achieved. High precision polishing of surfaces can be done using laser process. Currently, laser polishing has extended its applications from photonics to molds as well as bio-medical sectors. Conventional polishing techniques have many drawbacks such as less capability of polishing freeform surfaces, environmental pollution, long processing time, and health hazards for the operators. Laser polishing on the other hand eliminates all the mentioned drawbacks and comes as a promising technology that can be relied for smoothening of initial topography of the surfaces irrespective of the complexity of the surface. Majority of the researchers performed laser polishing on materials such as steel, titanium, and its alloys because of its low cost and reliability. This article gives a detailed overview of the laser polishing mechanism by explaining various process parameters briefly to get a better understanding about the entire polishing process. The advantages and applications are also explained clearly to have a good knowledge about the importance of laser polishing in the future.

关键词： laser polishing surface roughness process parameters mechanism

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激光熔覆NiCrAl-陶瓷涂层的显微组织研究

陈庆华,魏仑,龙晋明,李俊昌

《中国工程科学》 2001年第3卷第10期页码 64-71

摘要：

运用激光熔覆技术在40Cr钢表面制备了(TiO₂+B₂O₃+Al₂O₃+TiB₂)/NiCrAl金属陶瓷涂层，其中的TiB₂和Al₂O₃陶瓷颗粒在激光加工过程中原位反应生成；对熔覆层的组织、物相、元素分布和显微硬度分布特征进行了分析研究；熔覆层中的主相依次分别是γ-Ni,γ′,Al₂O₃和TiB₂，熔覆层的微观结构和硬度主要和激光处理参数和熔覆层化学组成有关^［1～9］；陶瓷相的原位生成和加入，大大改善了熔覆层的硬度和覆层/基体界面的结合性能。

关键词：激光熔覆金属陶瓷微观组织物相显微硬度

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Influence of the field humiture environment on the mechanical properties of 316L stainless steel repaired with Fe314

Lianzhong ZHANG, Dichen LI, Shenping YAN, Ruidong XIE, Hongliang QU

《机械工程前沿（英文）》 2018年第13卷第4期页码 513-519 doi: 10.1007/s11465-018-0503-0

摘要：

The mechanical properties of 316L stainless steel repaired with Fe314 under different temperatures and humidities without inert gas protection were studied. Results indicated favorable compatibility between Fe314 and 316L stainless steel. The average yield strength, tensile strength, and sectional contraction percentage were higher in repaired samples than in 316L stainless steel, whereas the elongation rate was slightly lower. The different conditions of humiture environment on the repair sample exerted minimal influence on tensile and yield strengths. The Fe314 cladding layer was mainly composed of equiaxed grains and mixed with randomly oriented columnar crystal and tiny pores or impurities in the tissue. Results indicated that the hardness value of Fe314 cladding layer under different humiture environments ranged within 419–451.1 HV_0.2. The field humiture environment also showed minimal impact on the average hardness of Fe314 cladding layers. Furthermore, 316L stainless steel can be repaired through laser cladding by using Fe314 powder without inert gas protection under different temperatures and humidity environments.

关键词： laser cladding repaired performance tensile strength temperature and humidity environment

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用于润湿性控制的Stavax 钢基材的皮秒激光表面纹理处理 Article

Xincai Wang, 郑宏宇, Yinchi Wan, Wenhe Feng, Yee Cheong Lam

《工程（英文）》 2018年第4卷第6期页码 816-821 doi: 10.1016/j.eng.2018.10.006

摘要：

在本文中，笔者采用皮秒激光来制造Stavax钢基板的表面纹理，此钢基板为制造各种高分子聚合物产品模具的关键材料。在Stavax 钢基板上主要有3种类型的表面纹理：周期性波纹、微凸块的双尺度分层二维阵列以及有纳米波纹的微坑阵列。经激光处理后的Stavax钢基板表面的润湿性从其原始的亲水性转变为疏水性，甚至在暴露于空气后具有超疏水性。研究结果清晰地表明，此超疏水性主要是由于表面纹理造成的。超快激光诱导的催化效果可能在改变表面化学性质方面起到次要作用，从而降低了表面能。随后，将金属磨具表面上的经激光处理的表面纹理通过高分子聚合物注射成型工艺复制到聚丙烯基底。由此，聚丙烯模具表面的润湿性从原始的亲水性变成疏水性。此开发工艺在改善塑料制品的湿润控制性和易清洗性方面具有一定潜能。

关键词：皮秒激光表面纹理处理 Stavax钢高分子聚合物疏水性

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Dimethicone-aided laser cutting of solar rolled glass

Wenyuan LI, Guojun ZHANG, Long CHEN, Yu HUANG, Youmin RONG, Zhangrui GAO

《机械工程前沿（英文）》 2021年第16卷第1期页码 111-121 doi: 10.1007/s11465-020-0615-1

摘要： Solar rolled glass, with one micro-structure surface and another roughness surface, can cause diffuse refraction of the focused laser spot, and this phenomenon restricts the application of laser manufacturing. In this study, laser cutting of solar rolled glass with a thickness of 2.5 mm was successfully achieved with the help of dimethicone to ensure laser focusing. Dimethicone was coated on the top surface of the rolled glass processing zone, and a bottom–up multilayer increment with the spiral line was applied to control the cutting path. Different viscosity values of dimethicone were considered. Results showed that surface quality increased as the viscosity increased until a certain threshold was reached; afterward, the surface quality decreased or directly caused the cutting to fail. The minimum surface roughness (3.26 µm) of the processed surface (chipping: Width≤113.64 µm, area 215199 µm ) was obtained when the dimethicone viscosity and laser pulse frequency were 1000 mm /s and 43 kHz (power 25.4 W), respectively. The micro-defects on the processed surface were few, and the edge chipping width and depth of the laser processed surface were small.

关键词： laser cutting solar rolled glass dimethicone viscosity surface quality

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Analysis and comparison of laser cutting performance of solar float glass with different scanning modes

Wenyuan LI, Yu HUANG, Youmin RONG, Long CHEN, Guojun ZHANG, Zhangrui GAO

《机械工程前沿（英文）》 2021年第16卷第1期页码 97-110 doi: 10.1007/s11465-020-0600-8

摘要： Cutting quality and efficiency have always been important indicators of glass laser cutting. Laser scanning modes have two kinds, namely, the spiral and concentric circle scanning modes. These modes can achieve high-performance hole cutting of thick solar float glass using a 532-nm nanosecond laser. The mechanism of the glass laser cutting under these two different scanning modes has been described. Several experiments are conducted to explore the effect of machining parameters on cutting efficiency and quality under these two scanning modes. Results indicate that compared with the spiral scanning mode, the minimum area of edge chipping (218340 µm ) and the minimum Ra (3.01 µm) in the concentric circle scanning mode are reduced by 9.4% and 16.4% respectively. Moreover, the best cutting efficiency scanning mode is 14.2% faster than that in the spiral scanning mode. The best parameter combination for the concentric circle scanning mode is as follows: Scanning speed: 2200 mm/s, number of inner circles: 6, and circle spacing: 0.05 mm. This parameter combination reduces the chipping area and sidewall surface roughness by 8.8% and 9.6% respectively at the same cutting efficiency compared with the best spiral processing parameters. The range of glass processing that can be achieved in the concentric circle scanning mode is wider than that in the spiral counterpart. The analyses of surface topography, white spots, microstructures, and sidewall surface element composition are also performed. The study concluded that the concentric circle scanning mode shows evident advantages in the performance of solar float glass hole cutting.

关键词： laser cutting solar float glass scanning mode surface quality cutting efficiency

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超短脉冲激光制造及表面加工微米器件 Review

于泳超, 白石, 王树同, 胡安明

《工程（英文）》 2018年第4卷第6期页码 779-786 doi: 10.1016/j.eng.2018.10.004

摘要：

超短脉冲激光在材料加工方面具有独特的优势。其对焦点之外区域的热影响效应非常有限，使超短脉冲激光可被应用于微米甚至纳米尺寸的精密加工。另外，非线性多光子效应使超短脉冲激光可以加工多种透明材料，包括玻璃以及透明高分子材料。基于这些特点，我们利用激光直写技术在高分子衬底上成功制造出了具有三维（3D）结构的高性能微型超级电容器（MSC），在0.1 mA·cm^–2的电流密度下表现出42.6 mF·cm^–2的峰值比电容。同时，也制造出了可用于探测多种“味道”的柔性传感器阵列。对传感器电极表面进行了不同的处理，如镀金、沉降氧化石墨烯（rGO）以及沉积聚苯胺（PANI）。通过对采集的数据进行主成分分析（PCA），这一传感器阵列可以成功地检测出样品内的不同物质。另外，在3D 结构玻璃微流体通道内由全飞秒激光加工出了具有2D周期性结构的纳米金属表面，可用于实时表面增强拉曼散射（SERS）的检测。全飞秒激光加工过程包括激光烧蚀、激光还原和激光诱导表面纳米工程。这些工作证明了超短脉冲激光在表面精密加工中的巨大潜力。

关键词：超短脉冲激光加工微米器件超级电容器电子舌表面增强拉曼光谱

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高强度合金抗疲劳应用技术研究与发展

越振业

《中国工程科学》 2005年第7卷第3期页码 90-94

摘要：

评述了超高强度钢、高强度A1合金和Ti合金表面完整性抗疲劳应用技术的研究和发展。高强度合金疲劳性能对应力集中敏感，不适当的加工工艺和切削热等造成的表面损伤和髙拉应力使其疲劳和应力腐蚀性能损失殆尽。先进的表面完整性加工尤其是表面改性可显著提高疲劳性能，如激光冲击使7475-T761拉-拉疲劳寿命提高约89%，7075-T6裂纹扩展速率降低到原来的1/1500;超声喷丸使超高强度钢低周疲劳强度提高约50%，Ti7A14Mo合金髙周疲劳强度提高约15%;表面超硬化可使Vasco X-2M齿轮钢接触疲劳寿命提高30～35倍等。

关键词：高强度合金表面完整性激光冲击表面超硬化

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Steady-state thermal-hydraulic analysis of SCWR assembly

LIU Xiaojing, CHENG Xu

《能源前沿（英文）》 2008年第2卷第4期页码 475-478 doi: 10.1007/s11708-008-0093-3

摘要： Among the six gen-IV reactor concepts recommended by the gen-IV international forum (GIF), supercritical water-cooled reactor (SCWR), the only reactor with water as coolant, achieves a high thermal efficiency and, subsequently, has economic advantages over the existing reactors due to its high outlet temperature. A thermal-hydraulic analysis of the SCWR assembly is performed in this paper using the modified COBRA-IV code. Two approaches to reduce the hot channel factor are investigated: decreasing the moderator mass flow and increasing the thermal resistance between moderator channel and its adjacent sub-channels. It is shown that heat transfer deterioration cannot be avoided in SCWR fuel assembly. It is, therefore, highly required to calculate the cladding temperature accurately and to preserve the fuel rod cladding integrity under heat transfer deterioration conditions.

关键词： cladding temperature assembly temperature coolant resistance